Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborate
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چکیده
The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra-fluorido-borate and triphenyl-phosphane in the presence of 1,2-bis-(pyridin-2-yl)ethyl-ene. The Ag(I) atom is tetra-hedrally coordinated by four P atoms from triphenyl-phosphane (PPh(3)) ligands. Due to symmetry, the tetra-fluorido-borate anion is disordered over three positions (each with one third occupancy). The tetra-fluorido-borate anion does not coordinate to the Ag(I) atom.
منابع مشابه
Tetrakis(triphenylphosphane-κP)silver(I) trifluoromethanesulfonate dichloromethane monosolvate
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